From my perspective the ace of pentacles can stand for new opportunities and if you get involved will enjoy as a result of the experience. so with regards to the question i would say that they find the person attractive and drawn to them. a definite positive card.
I am really curious about the spread myself. I see this comes up a lot. But I never seen a spread that ask the question, is it one you made yourself? As I said, just curious.
Short 'n round.
Needs to spend a penny on her appearance; or, Has spent a pretty penny on her appearance.
Places a low/high value on appearance.
She could make money with those looks (looks like a model, or a hooker).
She looks ace.
She'll wear a hole in your pocket.
She's got the goods.
What a pretty penny.
Head or Tail?
Aces represent the potential of the whole suit. She may look as if she's got potential for what the Pentacles represent in general---to be prosperous, down to earth, fertile, etc. Or the potential to progress to ultimately having the security represented in the 10 of Pentacles. You might even stretch to say he thinks she "looks like a million bucks", maybe.